Sudan I

Sudan I Basic information
Product Name:Sudan I
Synonyms:Oil-soluble yellow;Fast Orange R;Oil Orange A;SUDAN I C.I. NO.12055;Oilorgange;Sudanl=SudanYellow14;Sudan I, pure;Sudan I, 1-Phenylazo-2-naphthol
CAS:842-07-9
MF:C16H12N2O
MW:248.28
EINECS:212-668-2
Product Categories:Organics;Solvent Dyestuff;Dyes and Pigments;Solvents and Intermediates;Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:842-07-9.mol
Sudan I Structure
Sudan I Chemical Properties
Melting point 131-133 °C
Boiling point 391.35°C (rough estimate)
density 1.1077 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.5800 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Ethyl Acetate (Slightly)
form Powder
pka13.50±0.40(Predicted)
Colour Index 12055
color Orange to red or brown
Water Solubility 0.5 g/L (30 ºC)
Stability:Incompatible with strong oxidizing agents.
LogP5.51
CAS DataBase Reference842-07-9(CAS DataBase Reference)
IARC3 (Vol. 8, Sup 7) 1987
NIST Chemistry Reference2-Naphthalenol, 1-(phenylazo)-(842-07-9)
EPA Substance Registry SystemC.I. Solvent Yellow 14 (842-07-9)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 68-53-43-40-36/37/38
Safety Statements 61-46-36/37-22-36-26
WGK Germany 2
RTECS QL4900000
HS Code 32129000
Hazardous Substances Data842-07-9(Hazardous Substances Data)
Toxicitymmo-sat 300 ng/plate SCIEAS 236,933,87
MSDS Information
ProviderLanguage
C.I. 12055English
ACROSEnglish
Sudan I Usage And Synthesis
Chemical Propertiesorange-red powder
UsesA food azo-dye, a liver and urinary bladder carcinogen for rodents and a potent contact allergen and sensitizer for humans. Genotoxic and carcinogenic. Dyes and metabolites, Environmental Testing.
UsesA food azo-dye, a liver and urinary bladder carcinogen for rodents and a potent contact allergen and sensitizer for humans.
PreparationAniline diazo, and Naphthalen-2-ol?coupling.
DefinitionChEBI: Sudan I is an azo compound. It has a role as a dye. It is functionally related to a 2-naphthol.
General DescriptionDark reddish-yellow leaflets or orange powder. Slight odor.
Air & Water ReactionsAzo dyes can be explosive when suspended in air at certain concentrations. Insoluble in water.
Reactivity ProfileSudan I is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. Sudan I is incompatible with strong oxidizing agents and strong acids .
Fire HazardFlash point data for Sudan I are not available; however, Sudan I is probably combustible.
Flammability and ExplosibilityNotclassified
Safety ProfileExperimental reproductive effects. Questionable carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. Used for coloring hydrocarbon solvents, oils, fats, waxes, shoe and floor polishes, and gasoline
Purification MethodsCrystallise the dye from EtOH. It forms Cu and Ni salts. [Beilstein 16 H 162, 16 I 254, 16 II 70, 16 III 129, 16 IV 228.]
Properties and ApplicationsRed light yellow. Melting point 134 ℃. Soluble in ethanol (for orange), acetone and benzene, insoluble in water. The strong sulfuric acid for product red, diluted for orange, precipitation; In the hot strong hydrochloric acid solution for red, HCL after cooling for the crystallization variegated dark green, but released a few separate hydrogen: and C.I. Solvent Yellow and the same chemical structure. Used for dyeing and printing of polyester fibers.
StandardIroning FastnessLight FastnessPersperation FastnessWashing FastnessFadingStainFadingStainFadingStainISO4-533-4
Sudan I Preparation Products And Raw materials
Raw materialsAniline–>Aniline-2-sulfonic acid–>5-Oxo-1-(2-sulfophenyl)-2,5-dihydro-1H-pyrazole-3-carboxylic acid–>Aniline–>2-Naphthol
Preparation Products1-Amino-2-naphthol

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