| Tetrabutylammonium perchlorate Basic information |
| Product Name: | Tetrabutylammonium perchlorate |
| Synonyms: | TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE;Tetrabutylammonium perchlorate, contains max. 10% water, 99%;n,n,n-tributyl-1-butanaminiuperchlorate;TETRABUTYLAMMONIUM PERCHLORATE REAGENT;Tetrabutylammoniumperchlorate,min.98%;Four tetrabutylaMMoniuMperchlorate;TetrabutylaMMoniuM Perchlorate, 98.0%(T);Tetra-n-butylammonium perchlorate, 99+% |
| CAS: | 1923-70-2 |
| MF: | C16H36ClNO4 |
| MW: | 341.91 |
| EINECS: | 217-655-5 |
| Product Categories: | metal perchlorate salt;Ammonium SaltsSynthetic Reagents;Greener Alternatives: Catalysis;Phase Transfer Catalysts;Ammonium SaltsAnalytical Reagents;Electrochemistry;Supporting Electrolytes for Electrochemistry;Ammonium Polyhalides, etc. (Quaternary);Oxidation;Quaternary Ammonium Compounds;Synthetic Organic Chemistry;Detergents A to ZSynthetic Reagents;Detergents;Perchlorates |
| Mol File: | 1923-70-2.mol |
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| Tetrabutylammonium perchlorate Chemical Properties |
| Melting point | 211-215 °C |
| density | 1.0387 (rough estimate) |
| refractive index | 1.6800 (estimate) |
| solubility | acetonitrile: 0.1 g/mL, clear, colorless |
| form | Crystalline Powder |
| color | White |
| Water Solubility | Soluble in acetonitrile and ethanol. Very slightly soluble in water. |
| Sensitive | Hygroscopic |
| BRN | 3579274 |
| Stability: | Stable. Strong oxidizer – contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat. |
| CAS DataBase Reference | 1923-70-2(CAS DataBase Reference) |
| EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, perchlorate (1923-70-2) |
| Safety Information |
| Hazard Codes | O,Xi |
| Risk Statements | 5-8-36/37/38 |
| Safety Statements | 17-26-36-36/37/39 |
| RIDADR | UN 1479 5.1/PG 2 |
| WGK Germany | 3 |
| TSCA | Yes |
| HazardClass | 5.1 |
| PackingGroup | II |
| HS Code | 29239000 |
| Provider | Language |
|---|---|
| Tetrabutylammonium perchlorate | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Tetrabutylammonium perchlorate Usage And Synthesis |
| Chemical Properties | white powder |
| Uses | Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis. |
| Uses | Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements. |
| Uses | Tetrabutylammonium perchlorate is a polarographic supporting electrolyte. |
| General Description | Visit our Sensor Applications portal to learn more. |
| Purification Methods | Crystallise the perchlorate from EtOH ethyl acetate, from n-hexane or diethyl ether/acetone mixture, ethyl acetate or hot CH2Cl2. Dry it in a vacuum at room temperature over P2O5 for 24hours. [Anson et al. J Am Chem Soc 106 4460 1984, Ohst & Kochi J Am Chem Soc 108 2877 1986, Collman et al. J Am Chem Soc 108 2916 1986, Blau & Espenson J Am Chem Soc 108 1962 1986, Gustowski et al. J Am Chem Soc 108 1986, Ikezawa & Kutal J Org Chem 52 3299 1987, Beilstein 4 IV 557.] |
| Tetrabutylammonium perchlorate Preparation Products And Raw materials |
| Preparation Products | tetrabutylammonio, salt with 2,4,6-trinitrophenol (1:1) |