| Terbutryn Basic information |
| Product Name: | Terbutryn |
| Synonyms: | TERBUTREX;TERBUTRYN;TERNIT;SUNTER;n-(1,1-dimethylethyl)-n’-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine;PREBANE(R);N’-ETHYL-6-METHYLSULFANYL-N-TERT-BUTYL-1,3,5-TRIAZINE-2,4-DIAMINE;TERBUTRYN PESTANAL, 250 MG |
| CAS: | 886-50-0 |
| MF: | C10H19N5S |
| MW: | 241.36 |
| EINECS: | 212-950-5 |
| Product Categories: | Pyridazines;Agro-Products;Amines;Bases & Related Reagents;Heterocycles;Isotope Labelled Compounds;Nucleotides;Sulfur & Selenium Compounds;HERBICIDE;TA – TEPesticides&Metabolites;Alpha sort;Herbicides;Pesticides&Metabolites;Q-ZAlphabetic;Triazines;Alphabetic |
| Mol File: | 886-50-0.mol |
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| Terbutryn Chemical Properties |
| Melting point | 104-105°C |
| Boiling point | 154-160°C |
| density | 1.45 |
| refractive index | 1.5500 (estimate) |
| Fp | 2 °C |
| storage temp. | APPROX 4°C |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Powder |
| pka | 4.03±0.10(Predicted) |
| color | White |
| Water Solubility | 0.0025 g/100 mL |
| BRN | 611817 |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 886-50-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Terbutryn(886-50-0) |
| EPA Substance Registry System | Terbutryn (886-50-0) |
| Safety Information |
| Hazard Codes | Xi,N,Xn,F |
| Risk Statements | 36-50/53-20/21/22-11 |
| Safety Statements | 26-60-61-36/37-16 |
| RIDADR | UN 3077 9/PG 3 |
| WGK Germany | 2 |
| RTECS | XY4725000 |
| Hazardous Substances Data | 886-50-0(Hazardous Substances Data) |
| Toxicity | LC50 (96-hour) for rainbow trout 3 mg/L, bluegill sun?sh 4 mg/L, carp 4 mg/L and perch 4 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 2,500 mg/kg (Hartley and Kidd, 1987), 2,045 mg/kg (RTECS, 1985). |
| Provider | Language |
|---|---|
| 2-tert-Butylamino-4-ethylamino-6-methylthio-1,3,5-triazine | English |
| Terbutryn Usage And Synthesis |
| Description | Terbutin is a systemic and conductive herbicide, which can be used for pre-emergence and post-emergence weeding, and the effective period in the soil is 3-10 weeks. It is mainly used in winter wheat, barley, sorghum, sunflower, potatoes, peas, soybeans, peanuts and other crop fields to control perennial ryegrass, ryegrass and autumn germinating chickweed, marigolds, poppies, kangaroo, crabgrass, foxtail Wait. |
| Chemical Properties | solid |
| Uses | Selective herbicide for control of annual broad-leaved and grass weeds in wheat. |
| Uses | A labelled triazine herbicide. |
| Uses | A triazine herbicide. |
| Definition | ChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by a tert-butylamino and an ethylamino group at positions 2 and 4 respectively. |
| Synthesis | Cyanuric chloride reacts with ter-butylamine to generate 2,4-dichloro-6-tert-butylamino-1,3,5-triazine; then reacts with ethylamine to generate 2-chloro-4-ethylamino-6-tertiary Butylamino-1,3,5-triazine, and finally reacts with methyl mercaptan to generate Terbutryn. |
| Environmental Fate | Plant. In plants, the methylthio group is oxidized to hydroxy derivatives and by dealkylation of the side chains. Residual activity in soil is limited to approximately 3–10 weeks (Hartley and Kidd, 1987). |
| Terbutryn Preparation Products And Raw materials |
| Raw materials | Cyanuric chloride–>tert-Butylamine–>METHYL MERCAPTAN–>1,3,5-Triazine–>Terbutylazine |