Propineb

Propineb Basic information
Product Name:Propineb
Synonyms:AGROCOL(R);AIRONE(R);[[(1-METHYL-1,2-ETHANEDIYL)BIS[CARBAMO-DITHIOATO]](2-)]ZINC HOMOPOLYMER;(1-methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complex;Zinc 1,2-propylenebis(dithiocarbamate);ZINC PROPYLENEBISDITHIOCARBAMATE;PROPINEB;Zinc, (((1-methyl-1,2-ethanediyl)bis(carbamodithioato))(2-))-
CAS:12071-83-9
MF:C5H10N2S4
MW:226.41
EINECS:235-134-0
Product Categories:FUNGICIDE
Mol File:12071-83-9.mol
Propineb Structure
Propineb Chemical Properties
Melting point 157-159°C
storage temp. 0-6°C
solubility DMSO (Slightly, Heated)
form Solid
color Off-White to Light Beige
Merck 13,7911
CAS DataBase Reference12071-83-9(CAS DataBase Reference)
EPA Substance Registry SystemPropineb (12071-83-9)
Safety Information
Hazard Codes N
Risk Statements 51/53
Safety Statements 60-61
RIDADR UN3077 9/PG 3
RTECS ZH4950000
HS Code 29302000
ToxicityLD50 in male rats, rabbits, cats (mg/kg): 8500, >2500, >2500 orally (Grewe)
MSDS Information
ProviderLanguage
(1-Methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complexEnglish
Propineb Usage And Synthesis
Chemical PropertiesFaintly yellow crystals or powder; becomes dark when heated. Decomposes in the presence of strong acids or bases. Insoluble in most common solvents.
UsesAgricultural fungicide.
UsesPesticides and plant growth
UsesPropineb is a dithiocarbamate compound, which is used as a fungicide. Sensitization was reported in an agricultural worker.
DefinitionChEBI: A polymeric complex of zinc with the propylene 1,2-bis(dithiocarbamate) anionic ligand. A fungicide, it is used to control a wide range of fungal diseases, including downy mildew, brown rot, black rot, red fire, leaf spot, and blight in crops such as grape , tomatoes, potatoes, berries, citrus, rice and tea.
HazardToxic by ingestion.
Agricultural UsesFungicide: Used to control downy mildew, black rot, brown rot and other fungi on vines, apples, pears, citrus, berry fruit, stone fruit, tomatoes, potatoes, tobacco, vegetables, rice, ornamentals and tea. Not currently registered in the U.S. Used in more than a dozen European countries. There are more than 15 global suppliers.
Trade nameAIRONE®; ANTRACOL®; BAY®-46131; BAYER®-46131; LH 3012®; LH 30/Z®; MEZINEB®; PROPINEBE®; ZIPROMAT®
Contact allergensZiram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.
Propineb Preparation Products And Raw materials

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