2-Tridecanone

2-Tridecanone Basic information
Product Name:2-Tridecanone
Synonyms:2-Tridecankje;Mathyl undecyl kepoje;2-TRIDECANONE FOR SYNTHESIS 50 G;2-Tridecanone 99%;Tridecanone-2;N-DECYL ETHYL KETONE;METHYL N-UNDECYL KETONE;ETHYL N-DECYL KETONE
CAS:593-08-8
MF:C13H26O
MW:198.34
EINECS:209-784-0
Product Categories:Building Blocks;C13 to C14;Carbonyl Compounds;Chemical Synthesis;Humulus lupulus (Hops);Ketones;Nutrition Research;Organic Building Blocks;Phytochemicals by Plant (Food/Spice/Herb)
Mol File:593-08-8.mol
2-Tridecanone Structure
2-Tridecanone Chemical Properties
Melting point 24-27 °C (lit.)
Boiling point 134 °C/10 mmHg (lit.) 263 °C (lit.)
density 0.822 g/mL at 25 °C (lit.)
FEMA 3388 | 2-TRIDECANONE
refractive index n20/D 1.435(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form powder to lump to clear liquid
color White or Colorless to Light orange to Yellow
Odorat 10.00 % in dipropylene glycol. fatty waxy dairy milky coconut nutty herbal earthy
Odor Typewaxy
JECFA Number298
BRN 1757402
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
LogP5.16
CAS DataBase Reference593-08-8(CAS DataBase Reference)
NIST Chemistry Reference2-Tridecanone(593-08-8)
EPA Substance Registry System2-Tridecanone (593-08-8)
Safety Information
Hazard Codes N
Risk Statements 50
Safety Statements 23-24/25-61
RIDADR UN 3077 9/PG 3
WGK Germany 2
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29141900
MSDS Information
ProviderLanguage
2-TridecanoneEnglish
SigmaAldrichEnglish
ALFAEnglish
2-Tridecanone Usage And Synthesis
Chemical Properties2-Tridecanone has a warm, oily, herbaceous odor reminiscent of nut.
Chemical Propertieswhite to slightly yellow crystalline solid
OccurrenceReported found in coconut and palm oils; also in the oil of Schizandra nigra Max. (Matsubusa). Also reported found in American cranberry, rabbiteye blueberry, raspberry, other types of ginger, blue cheeses, cheddar cheese, Swiss cheese, Camembert cheese, Gruyere cheese, Limburger cheese, parmesan cheese, other cheeses, grapefruit juice, fejoia fruit, onion, shallot, leek, chive, ginger, butter, milk, cream, milk powder, roast chicken, chicken fat, cooked beef and mutton, pork liver, hop oil, cognac, rum, coconut meat, mango, rice, corn oil, wort, dried bonito, mountain papaya and maté.
Uses2-Tridecanone was used to study the impact of soil amendments in onion bulbs.
PreparationBy heating a mixture of lauric acid and acetic acid over thorium oxide at 450°C.
DefinitionChEBI: A methyl ketone that is tridecane in which the methylene hydrogens at position 2 are replaced by an oxo group.
Taste threshold valuesTaste characteristics at 10 ppm: fatty and earthy with a fatty mouthfeel and with a dairy, ketonic, waxy, creamy, cheesy, dairy and coconut.
General DescriptionWhite crystalline solid.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileKetones, such as 2-Tridecanone, are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Fire Hazard2-Tridecanone is combustible.
2-Tridecanone Preparation Products And Raw materials
Raw materialsLauric acid–>Thorium dioxide–>12-Tridecen-2-one–>Stannane, tris(phenylmethyl)-–>12-TRICOSANONE–>1-Iodononane–>1-Decyne–>(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE–>1-Tridecene–>Methyl vinyl ketone–>1-Decanol
Preparation Products4-methylpentadecane–>(R)-3-Hydroxy Myristic Acid–>Pentanoic acid, 1-methyldodecyl ester

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