ORANGE I

ORANGE I Basic information
Product Name:ORANGE I
Synonyms:sodiumazo-alpha-naphtholsulphanilate;tertracidorangei;tropaeolin1;NAPHTHOL ORANGE;ORANGE I;ORANGE1;TROPAEOLIN 000 NO 1;TROPAEOLIN OOO-1
CAS:523-44-4
MF:C16H11N2NaO4S
MW:350.32
EINECS:208-346-6
Product Categories:Organics
Mol File:523-44-4.mol
ORANGE I Structure
ORANGE I Chemical Properties
Melting point 260 °C (decomp)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
Colour Index 14600
color Red to Very Dark Red
Merck 14,6857
BRN 3826844
IARC3 (Vol. 8, Sup 7) 1987
EPA Substance Registry SystemC.I. Acid Orange 20 monosodium salt (523-44-4)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
RTECS DB7085000
HS Code 32041200
Hazardous Substances Data523-44-4(Hazardous Substances Data)
ToxicityLD50 intraperitoneal in rat: 1gm/kg
MSDS Information
ORANGE I Usage And Synthesis
Chemical PropertiesCrystalline
UsesA labeled form of alpha-Naphthol Orange, also known as Acid Orange 20, which is an organic azo dye.
DefinitionChEBI: CI Acid Orange 20 is an organic molecular entity.
Preparation4-Aminobenzenesulfonic acid diazo, and Naphthalen-1-ol?coupling.
Purification MethodsPurify the dye by dissolving it in the minimum volume of H2O, adding, with stirring, a large excess of EtOH. The salt separates as orange needles. It is collected by centrifugation or filtration, washed with absolute EtOH (3x) and Et2O (2x) in the same way and dried in a vacuum desiccator over KOH. The free acid can be recrystallised from EtOH. [Slotta & Franke Chem Ber 64 86 1931, Beilstein 16 H 275, 16 II 117, 16 IV 410.] The purity can be checked by titration with titanium chloride [Klotz J Am Chem Soc 68 2299 1946].
Properties and Applicationsorange. Soluble in water for palm light orange, slightly soluble in ethanol, acetone, insoluble in most organic solvents. The strong sulfuric acid for purple, diluted into palm orange, red with purple precipitation. Its water solution to join strong hydrochloric acid for orange brown; Add sodium hydroxide in red. Used for wool, silk fiber dyeing, etc. Also used in leather dyeing and indicator.
ORANGE I Preparation Products And Raw materials

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