Copper(II) phthalocyanine

Copper(II) phthalocyanine Basic information
Product Name:Copper(II) phthalocyanine
Synonyms:Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)- Copper, [phthalocyaninato(2-)]-;phthalocyanine blueB15:0;Pigment Blue 15 (purified by sublimation);calcotonebluegp;ceresbluebhr;chromatexbluebn;ciingrainblue2;cipigmentblue15
CAS:147-14-8
MF:C32H16CuN8
MW:576.07
EINECS:205-685-1
Product Categories:Blue needle crystal;Organometallics;electronic;Classes of Metal Compounds;Cu (Copper) Compounds;Functional Materials;Phthalocyanines;Phthalonitriles & Naphthalonitriles;Transition Metal Compounds;Electroluminescence;Dyes and Pigments;INORGANIC & ORGANIC CHEMICALS;oled materials
Mol File:147-14-8.mol
Copper(II) phthalocyanine Structure
Copper(II) phthalocyanine Chemical Properties
Melting point 600°C (dec.)
density 1.62[at 20℃]
storage temp. Inert atmosphere,Room Temperature
Colour Index 74160
form Fine Crystalline Powder
color Dark blue
Odorodorless
Water Solubility <0.1 g/100 mL at 20 ºC
λmax602nm(CHCl3)(lit.)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Merck 14,2520
BRN 4121848
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKeyXCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP-1 at 23℃
NIST Chemistry ReferenceCopper phthalocyanine(147-14-8)
EPA Substance Registry SystemC.I. Pigment Blue 15 (147-14-8)
Absorptionλmax 678 nm (DMF)
Safety Information
Safety Statements 22-24/25
WGK Germany 
RTECS GL8510000
TSCA Yes
HS Code 32041300
Hazardous Substances Data147-14-8(Hazardous Substances Data)
ToxicityLD50 intraperitoneal in rat: > 3gm/kg
MSDS Information
ProviderLanguage
(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copperEnglish
SigmaAldrichEnglish
ACROSEnglish
ALFAEnglish
Copper(II) phthalocyanine Usage And Synthesis
DescriptionCopper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.
Chemical Propertiesdark blue fine crystalline powder
UsesCopper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.
ApplicationCopper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.
General DescriptionCopper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.
Flammability and ExplosibilityNotclassified
Properties and ApplicationsTEST ITEMSSPECIFICATIONAPPEARANCEBLUE POWDERSHADEREDDISHHEAT RESISTANCE300 °C minLIGHT FASTNESS7-8ACID RESISTANCE5ALKALI RESISTANCE5FASTNESS TO BLEEDING5OIL ABSORPTION40-45%SPECIFIC SURFACE29 m /gDENSITY1.60 g/cm 3RESIDUE ON 80 MESH5.0% maxWATER SOLUBLE1.0% maxVOLATITE 105 °C1.0% maxTINTING STRENGTH100-105 %
Purification MethodsPrecipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]
Copper(II) phthalocyanine Preparation Products And Raw materials
Raw materialsSodium hydroxide–>Hydrochloric acid–>Sulfuric acid–>Ammonium chloride–>Urea–>Chlorine–>FUMING SULFURIC ACID–>Xylene–>Calcium chloride–>Copper(I) chloride–>Phthalic anhydride–>Potassium iodide–>1,2,4-Trichlorobenzene–>Ammonium molybdate tetrahydrate–>Ammonium molybdate–>Copper(II) chloride dihydrate–>Copper(II) chloride dihydrate–>Zinc stearate
Preparation ProductsChromium(III) oxide–>Amino resin paint–>Pigment Geen 7–>Various color alkyd primer–>Various color amino baking enamel A04-9–>Alkyd enamel–>Various color nitrocellulose exterior enamel Q04-2–>POLYSULFONE–>Reactive Blue 14–>Direct Blue 86–>4923 Spirit Light Fast Ball-pen Blue GR–>Ferro phthalocyanine green–>Reactive Turquoise Blue Kn-G–>Reactive Blue 231–>Direct Blue 199–>Sulphur Green 14–>ACID BLUE 249–>REACTIVE BLUE 15

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