Basic Red 9

Basic Red 9 Basic information
Product Name:Basic Red 9
Synonyms:4-((4-aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl)-benzenaminm;4,4’-((4-imino-2,5-cyclohexadien-1-ylidene)methylene)dianilinemonohydrochlor;4,4’-((4-imino-2,5-cyclohexadien-1-ylidene)methylene)dianilinemonohydrochlorid;4,4’,4″-triaminotriphenylmethanehydrochloride;4,4’,4″-triaminotriphenylmethan-hydrochlorid;4-[(4-aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl]-benzenaminm;alpha-(p-aminophenyl)-alpha-(4-imino-2,5-cyclohexadien-1-ylidene)-4-toluidin;basicparafuchsine
CAS:569-61-9
MF:C19H17N3.ClH
MW:323.82
EINECS:209-321-2
Product Categories:Triphenylmethane;Dyes and Pigments;Stains and DyesDerivatization Reagents TLC;Steroids, Terpenes, Lipids, Bile acids;Analytical Reagents;Microscopy Reagents;TLC Visualization Reagents (by application);Stains and Dyes
Mol File:569-61-9.mol
Basic Red 9 Structure
Basic Red 9 Chemical Properties
Melting point 250 °C
Boiling point 479.57°C (rough estimate)
density 0.999 g/mL at 20 °C
refractive index n20/D 1.334
Fp 11 °C
storage temp. Store at RT.
solubility ethanol: soluble1mg/mL
Colour Index 42500
form Solid
color metallic green
PH Range1.0 – 3.1, purple to red
Water Solubility 10 g/L (25 ºC)
λmax545 nm
BRN 4164603
Stability:Stable. Incompatible with strong oxidizing agents.
Biological ApplicationsDetecting breast cancer; treating pathogens
InChIKeyJUQPZRLQQYSMEQ-UHFFFAOYSA-N
CAS DataBase Reference569-61-9
IARC2B (Vol. 57, 99) 2010
EPA Substance Registry SystemC.I. Basic Red 9, monohydrochloride (569-61-9)
Safety Information
Hazard Codes F,T,Xn
Risk Statements 40-45-11
Safety Statements 7-16-53-45-36/37
RIDADR UN 2924 3/PG 2
WGK Germany 3
RTECS CX9850000
TSCA Yes
HS Code 32041300
Hazardous Substances Data569-61-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
4,4′-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochlorideEnglish
SigmaAldrichEnglish
ACROSEnglish
ALFAEnglish
Basic Red 9 Usage And Synthesis
Chemical Propertiesgreen crystalline powder
Chemical PropertiesC.I. Basic red 9 is a colorless to red crystalline solid or green powder.
UsesPararosaniline Hydrochloride is a red dye used for textiles. Dyes and metabolites, Environmental Testing.
UsesAntischistosoma.
DefinitionChEBI: A hydrochloride that is the monohydrochloride of 4,4′-[(4-iminocyclohexa-2,5-dien-1-ylidene)methanediyl]dianiline. One of the major constituents of Basic fuchsin, together with rosanilin, magenta II and new fuchsin.
Preparationcommonly known as (Para Magenta, Para Rosaniline) (a) 4-(4-Aminobenzyl)benzenamine?and aniline, Aniline hydrochloride, the difficulties and ferric chloride in 170 ℃ heating hours;?(b) aniline,p-Methylaniline and its hydrochloride and iron, ferrous chloride or 1-Nitrobenzene?heating; (C) aniline?and p-Methylaniline?was treated with arsenic oxide; (d) aniline?tetrachloride carbon heat.
General DescriptionColorless to red crystals or green powder.
Air & Water ReactionsInsoluble in water.
Health HazardACUTE/CHRONIC HAZARDS: When heated to decomposition Basic Red 9 emits very toxic fumes of hydrogen chloride and nitrogen oxides.
Fire HazardFlash point data for Basic Red 9 are not available; however, Basic Red 9 is probably combustible.
Safety ProfileConfirmed carcinogen with experimental carcinogenic and tumorigenic data. Mildly toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of HCl and NOx.
Potential ExposureUsed as a dye for textiles, paper; printing, computer and photo imaging inks, leather, and many consumer products; as a microbiological/microscopy stain for bacilli, including tubercle and influenza.
CarcinogenicityBasic red 9 monohydrochloride is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals.
ShippingUN 3143 Dyes, solid, toxic, n.o.s., or dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.
Properties and Applicationscolourful red blue light. Slightly soluble in cold water, soluble in hot water for red, easily soluble in ethanol is cherry red. The strong sulfuric acid for yellow brown, after dilute for purple. Used in the manufacture of blue ink, also can dye tannins mordant dyeing cotton.
Standard( Cotton )Light FastnessPersperation FastnessIroning FastnessSoapingFadingStainFadingStainFadingStainA211
IncompatibilitiesMay be combustible; powder or liquid may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Basic Red 9 Preparation Products And Raw materials
Raw materialsAniline–>4,4′-Methylenedianiline–>Nitrobenzene–>p-Toluidine
Preparation ProductsAcid Blue 93–>Solvent Violet 8–>OPAL BLUE SS–>Solvent Blue 66–>BASIC FUCHSIN LEUCONITRILE

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