Acid Green 50

Acid Green 50 Basic information
Product Name:Acid Green 50
Synonyms:ACID GREEN 50;[4-[4-(dimethylamino)-alpha-(2-hydroxy-3,6-disulphonato-1-naphthyl)benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium inner salt sodium salt;WOOL GREEN S;12078green;acidalwoolgreenbs;acidbrilliantgreenbs;AcidgreenBS;acidleathergreens
CAS:3087-16-9
MF:C27H27N2NaO7S2
MW:578.63
EINECS:221-409-2
Product Categories:Dyes and Pigments
Mol File:3087-16-9.mol
Acid Green 50 Structure
Acid Green 50 Chemical Properties
Melting point >300°C
density 0.541[at 20℃]
storage temp. Refrigerator
solubility DMSO (Slightly), Methanol (Slightly)
form Powder
Colour Index 44090
color Dark brown or black
Water Solubility 492.554g/L at 28℃
Stability:Incompatible with strong oxidizing agents.
LogP0.595 at 25℃
CAS DataBase Reference3087-16-9(CAS DataBase Reference)
EPA Substance Registry SystemMethanaminium, N-[4-[[4-(dimethylamino)phenyl](2-hydroxy-3,6-disulfo-1-naphthalenyl)methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, inner salt, monosodium salt (3087-16-9)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 36/37/39
WGK Germany 3
RTECS BQ1150000
HS Code 32041200
Toxicityrat,LD50,oral,2gm/kg (2000mg/kg),Scientia Pharmaceutica. Vol. 47, Pg. 39, 1979.
MSDS Information
ProviderLanguage
[4-[4-(Dimethylamino)-alpha-(2-hydroxy-3,6-disulphonato-1-naphthyl)benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium inner salt sodium saltEnglish
SigmaAldrichEnglish
ACROSEnglish
Acid Green 50 Usage And Synthesis
Chemical Propertiessolid
UsesAcid Green 50 is a food coloring in drinks and candles. Also used on living cells as protein stains for chemical and molecular analyses.
Preparation(a)4-(Dichloro(4-(dimethylamino)phenyl)methyl)-N,N-dimethylbenzenamine and Naphthalen-2-ol condensation, with hair smoke sulphonated sulfuric acid, and translated into sodium salt; (b) Bis (4 – (dimethylamino) phenyl) methanoland ?3-Hydroxynaphthalene-2,7-disulfonic acid (or 7-Hydroxynaphthalene-1,3-disulfonic acid) condensation, product oxidation, and translated into sodium salt.
Purification MethodsCrystallise it from EtOH/water (1:1, v/v). Irritant. [Beilstein 14 II 574.]
Properties and Applicationsblue light green. Blue-green powder. Soluble in cold water, easily soluble in hot water (green blue), soluble in ethanol (turquoise blue). Meet strong sulfuric acid as orange, a green light amber after diluted. Mainly used for wool, polyamide, silk dyeing. Also used in leather, food, medicine and cosmetics of shading.
StandardLight FastnessSoapingPersperation FastnessOxygen bleachingFastness to seawaterFadingStainFadingStainFadingStainISO32341531AATCC2-33321133
Acid Green 50 Preparation Products And Raw materials
Raw materialsDisodium 2-naphthol-3,6-disulfonate–>4,4′-Bis(dimethylamino)benzhydrol–>2-Naphthol-6,8-disulfonic acid–>4-(dichloro(4-(dimethylamino)phenyl)methyl)-N,N-dimethylbenzenamine–>2-Naphthol

دیدگاهی بنویسید

نشانی ایمیل شما منتشر نخواهد شد. بخش‌های موردنیاز علامت‌گذاری شده‌اند *