Acid Green 25

Acid Green 25 Basic information
Product Name:Acid Green 25
Synonyms:c.i.acidgreen25;d&cgreen;d&cgreen5;d&cgreen8;Disodiumsaltof2,2’-[9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis-[5-methylbenzenesulfonicacid];zelenalizarinovabrilantnig-extra;zelenkysela25;Weak Acid Green GS
CAS:4403-90-1
MF:C28H23N2NaO8S2
MW:602.61
EINECS:224-546-6
Product Categories:Organics;Aminoanthraquinones;Anthraquinones;Dyes and Pigments;A;Stains and Dyes;Stains&Dyes, A to
Mol File:4403-90-1.mol
Acid Green 25 Structure
Acid Green 25 Chemical Properties
Melting point 235-238 °C(lit.)
form neat
Colour Index 61570
color Bluish green powder
Water Solubility 36 g/L (20 ºC)
Merck 14,252
InChIKeyFPAYXBWMYIMERV-UHFFFAOYSA-L
LogP-1.966 at 20℃
EPA Substance Registry SystemC.I. Acid Green 25 (4403-90-1)
Safety Information
Hazard Codes N
Risk Statements 51/53-36
Safety Statements 24/25-61-26
RIDADR UN 3077 9 / PGIII
WGK Germany 2
RTECS DB5044000
HS Code 32041200
Hazardous Substances Data4403-90-1(Hazardous Substances Data)
ToxicityLD50 orl-rat: >10 g/kg GTPZAB 28(7),53,84
MSDS Information
ProviderLanguage
Disodium 2,2′-(9,10-dioxoanthracene-1,4-diyldiimino)bis(5-methylsulphonate)English
SigmaAldrichEnglish
ACROSEnglish
Acid Green 25 Usage And Synthesis
Chemical Propertiesdark green powder
UsesAcid Green 25 (cas# 4403-90-1) is an organic acid dye. Acid green 25 can undergo colour when co-intercalated with acid yellow 25 into the interlayer of ZnAl layered double hydroxides.Dyes and metabolites.
UsesFor nylon sutures: Fed. Regist. 42, 52395 (1977). Permitted for use in drugs and cosmetics, excluding use in eye area: ibid. 47, 49628 (1982).
Preparation(a) ?anthracene-1,4,9,10-tetraol?or 1,4-Dihydroxyanthracene-9,10-dione and anthracene-1,4,9,10-tetraol?mixture?with 2 moles of p-Methylaniline in the presence of boric acid condensation; (b) 1,4-Dichloroanthracene-9,10-dione and 2 Moore’s p-Methylaniline?condensation, its product (C.I. Solvent Green 3, C.I. 61565) products, and translate into sodium salt.
General DescriptionFine black or green powder.
Air & Water ReactionsSlightly soluble in water.
Reactivity ProfileAcid Green 25 is incompatible with strong oxidizing agents. .
Fire HazardFlash point data for Acid Green 25 are not available. Acid Green 25 is probably combustible.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by ingestion. Askin and severe eye irritant.
When heated to decomposition it emits very toxic fumesof NOx, SOx, and Na2O.
Purification MethodsPurify it by salting out three times from an aqueous solution with sodium acetate, followed by repeated extraction with EtOH [McGrew & Schneider J Am Chem Soc 72 2547 1950]. It is a green powder that is slightly soluble in Me2CO, EtOH and pyridine. It is soluble in conc H2SO4 to give a blue solution that becomes turquoise on dilution. [Allen et al. J Org Chem 7 63 1942, Beilstein 14 H 725.]
Properties and Applicationsblue light green. Green powder. Soluble in water, no solution at room temperature gather the tendency. Soluble in o-chlorophenol, slightly soluble in acetone, ethanol, Pyridine, insoluble in chloroform, toluene. The strong sulfuric acid dyes shows blackish green color, diluted Tracy turn blue; In nitric acid are brown. The little blue water solution, and a blue hydrochloric acid; Add sodium hydroxide is blue light green. Used for wool, polyamide, silk and their blended fabric dyeing and printing. Can also be used in leather, paper, cosmetics, soap, wood, electrical-controlled aluminum and biological color.
StandardLight FastnessSoapingPersperation FastnessOxygen bleachingFastness to seawaterFadingStainFadingStainFadingStainISO63242143-4AATCC54433344
Acid Green 25 Preparation Products And Raw materials
Raw materials1,4-Dihydroxyanthraquinone–>p-Toluidine–>1,4-DICHLOROANTHRAQUINONE–>1,4-DICHLOROANTHRAQUINONE–>Solvent Green 3–>1,4-Dihydroxyanthraquinone–>p-Toluidine

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