Rhodium(III) sulfate

Rhodium(III) sulfate Basic information
Product Name:Rhodium(III) sulfate
Synonyms:RHODIUM SULFATE;RHODIUM(III) SULFATE;rhodium(iii)sulfatesolution;sulfuricacid,rhodium(3++)salt(3:2);dirhodium trisulphate;Rhodium plating solution;RHODIUM(III) SULFATE SOLUTION, CA. 8% (W T/WT) RH IN WATER;Rhodium Sulphate
CAS:10489-46-0
MF:H2O4RhS
MW:200.98
EINECS:234-014-5
Product Categories:chemical reaction,pharm,electronic,materials;Materials Science;Metal and Ceramic Science;Rhodium Salts;Inorganics;Metal and Ceramic Science;Rhodium Salts;Salts
Mol File:10489-46-0.mol
Rhodium(III) sulfate Structure
Rhodium(III) sulfate Chemical Properties
Melting point decomposes at >500℃ [KIR82]
Boiling point 99℃[at 101 325 Pa]
density 1.217 g/mL at 25 °C(lit.)
vapor pressure 21.4hPa at 20℃
RTECS FF9335000
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form red-yellow solid
Water Solubility Miscible with water, ethanol and with a 3:1 ethanol/water mixture.
Exposure limitsACGIH: TWA 0.2 mg/m3
OSHA: TWA 1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 1 mg/m3
CAS DataBase Reference10489-46-0(CAS DataBase Reference)
EPA Substance Registry SystemSulfuric acid, rhodium(3+) salt (3:2) (10489-46-0)
Safety Information
Hazard Codes O,T,C
Risk Statements 49-8-23/24/25-34
Safety Statements 53-23-36/37/39-45
RIDADR UN3264
WGK Germany 3
TSCA Yes
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
Rhodium(III) sulfateEnglish
SigmaAldrichEnglish
ALFAEnglish
Rhodium(III) sulfate Usage And Synthesis
DescriptionWhen heated to decomposition, this product can emit acid mists and toxic gases (including oxides of sulphur and rhodium compounds). This product is not compatible with bases, halides, water, cyclopentadiene, cyclopentanone, oxime, nitroaryl amines, haxalithium disilicide, phosphorus (III) oxide, chlorine bromine pentafluoride, trifluoride, and oxygen difluoride (OF2). Avoid contact with metals. This product can react with water to generate heat.
Chemical Propertiesreddish yellow solid; ~8% aqueous solution [ALD94] [KIR82]
UsesRhodium(III) sulfate is used as plating reagents and additives for noble metal. It is also used for fancy plating rhodium in jewellery and horologe. Further, it is used for decorative applications.
General DescriptionRhodium(III) sulfate is an anhydrous metal sulfate that is formed by oxidizing rhodium with concentrated sulphuric acid. It is a red crystal that forms a hydrated solution at high temperatures. It is majorly used in the production of high performance coatings by electroplating technique.
Rhodium(III) sulfate Preparation Products And Raw materials

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