| L(-)-10-Camphorsulfonyl chloride Basic information |
| Product Name: | L(-)-10-Camphorsulfonyl chloride |
| Synonyms: | L(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-CAMPHOR-10-SULFONYL CHLORIDE;(1R)-(-)-10-CAMPHORSULFONYL CHLORIDE;(1R)-(-)-CAMPHOR-10-SULPHONYL CHLORIDE;(1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE;(1R)-CAMPHOR-10-SULFONIC ACID CHLORIDE;(1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE;(-)-10-CAMPHORSULFONYL CHLORIDE |
| CAS: | 39262-22-1 |
| MF: | C10H15ClO3S |
| MW: | 250.74 |
| EINECS: | 628-057-2 |
| Product Categories: | Peptide;Intermediates & Fine Chemicals;Pharmaceuticals;Sulfonyl Chlorides;chiral;Chiral Reagents;Bicyclic Monoterpenes;Biochemistry;for Resolution of Alcohols & Thiols;for Resolution of Bases;Optical Resolution;Synthetic Organic Chemistry;Terpenes |
| Mol File: | 39262-22-1.mol |
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| L(-)-10-Camphorsulfonyl chloride Chemical Properties |
| Melting point | 66-68 °C(lit.) |
| alpha | -33 º (c=3, chloroform) |
| Boiling point | 349.4±15.0 °C(Predicted) |
| density | 1.331±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Acetone, Dichloromethane, Ethyl Acetate, Methanol |
| form | Solid |
| color | White |
| optical activity | [α]18/D 33°, c = 3 in chloroform |
| Water Solubility | Decomposes |
| Sensitive | Moisture Sensitive |
| BRN | 3205975 |
| InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
| CAS DataBase Reference | 39262-22-1(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 10-21 |
| HazardClass | 8 |
| PackingGroup | II |
| HS Code | 29147090 |
| Provider | Language |
|---|---|
| (1R)-Camphor-10-sulfonic acid chloride | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| L(-)-10-Camphorsulfonyl chloride Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde |
| Uses | L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation. |
| Uses | A chiral derivative of Camphor. |
| Uses | A chiral derivative of Camphor |
| Purification Methods | If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.] |
| L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials |