3-Iodotoluene

3-Iodotoluene Basic information
Product Name:3-Iodotoluene
Synonyms:3-Methyl-iodobenzene;3-Iodotoluene,1-Iodo-3-methylbenzene;3-lodotoluene;3-iodotoiuene;1-iodo-3-methyl-benzen;M-IODOTOLUENE;3-methylphenyliodide;Benzene,1-iodo-3-methyl-
CAS:625-95-6
MF:C7H7I
MW:218.04
EINECS:210-918-5
Product Categories:Iodine Compounds;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:625-95-6.mol
3-Iodotoluene Structure
3-Iodotoluene Chemical Properties
Melting point -27°C
Boiling point 80-82 °C10 mm Hg(lit.)
density 1.698 g/mL at 25 °C(lit.)
refractive index n20/D 1.604(lit.)
Fp 180 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form clear liquid
Specific Gravity1.700 (20/4℃)
color Colorless to Red to Green
Water Solubility Not miscible in water. Soluble in benzene, alcohol and ether.
Sensitive Light Sensitive
BRN 1903634
CAS DataBase Reference625-95-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-iodo-3-methyl-(625-95-6)
EPA Substance Registry Systemm-Iodotoluene (625-95-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-36/37/39-27
RIDADR UN 2810
WGK Germany 2
RTECS DA3440000
TSCA T
HazardClass IRRITANT
HS Code 29039990
MSDS Information
ProviderLanguage
3-IodotolueneEnglish
SigmaAldrichEnglish
ACROSEnglish
ALFAEnglish
3-Iodotoluene Usage And Synthesis
Chemical Propertiesclear colorless to slightly yellow liquid
Uses3-Iodotoluene (1-Iodo-3-methylbenzene) was used in the preparartion of indene derivatives.
Usessuzuki reaction
Synthesis Reference(s)The Journal of Organic Chemistry, 45, p. 3728, 1980 DOI: 10.1021/jo01306a041
3-Iodotoluene Preparation Products And Raw materials
Raw materials2,5-DIIODOTOLUENE–>Iodine, bis(acetato-κO)(3-methylphenyl)-–>Benzene, 1-iodyl-3-methyl-–>Benzenediazonium, 3-methyl-, tetrafluoroborate(1-)–>lithium p-toluenesulphonate–>M-TOLYLMAGNESIUM BROMIDE–>Allyltrimethylsilane–>3-Tolylboronic acid–>m-Toluidine–>3-Bromotoluene
Preparation ProductsN,N’-Bis(3-methylphenyl)-N,N’-bis(phenyl)benzidine–>2-Iodotoluene–>4-iodo-2-Methylbenzoic acid–>4-(3′-Methylphenyl)amino-3-pyridinesulfonamide–>3-methylphenethyl bromide–>3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene–>1-METHYLANTHRACENE–>3-Phenyltoluene

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